A Comprehensive Review of Functional Nanomaterial-based Catalysts for Enhanced Biodiesel Production and Environmental Sustainability
Sodiq Akinola Muraina
C. Eugene Bennett Department of Chemistry, Ladoke Akintola University of Technology, Ogbomosho, Oyo State, Nigeria.
Julius Odemi Brown
Department of Marine Biology, University of Lagos, Nigeria.
Rufus Fidelis Ojuoluwa *
Department of Quantity Surveying, Moshood Abiola Polytechnic, Abeokuta, Ogun State, Nigeria.
Ige Hakeem Adeyemi
University of Ilorin Department of Material and metallurgical Engineering, Nigeria.
Confidence Adimchi Chinonyerem
Abia State Polytechnic, Nigeria.
*Author to whom correspondence should be addressed.
Abstract
With the global shift to renewable energy sources, there has been growing interest in biodiesel, which is a more environmentally and economically sustainable alternative to fossil fuels. Nevertheless, conventional catalytic materials currently used in biodiesel production processes are faced with efficiency, stability, soap formation, and environmental problems. Thus, this paper gives a scientific review of functional nanomaterial catalysts which aim to improve biodiesel production and, at the same time, ensure sustainability in the environment. A broad array of nanomaterials and their hybrids has been discussed, such as metal oxide nanoparticles, carbon nanomaterials, magnetic nanocatalysts, mesoporous nanomaterials, and more advanced hybrid functional nanomaterials. These nanocatalysts possess high surface areas, optimal porosity, increased mass transfer, strong base and acid functionalities, and high catalytic recyclability, which allow faster and more eco-friendly transformation of raw materials to biodiesel. The review distils information gathered from cutting-edge experimental work, pointing to the efficacy afforded by functional nanomaterials to transesterification and esterification reaction efficiency, catalyst stability, and waste avoidance. Of paramount importance is placing the work against the background of environmentally sustainable methods of synthesis, catalyst recyclability and recovery, and the relevance of nanocatalysis to sustainable global initiatives. The study picks up essential scientific trends, efficiency deficits, toxicity considerations, and the prospects offered by cutting-edge nanostructures, functionalization, and sustainable nanotechnology to scale up biodiesel. it has been made clear by the review that nanomaterials-based catalysts demonstrate great potential to improve biodiesel production, and it is expected to significantly influence new innovative approaches on the global level to obtain clean and efficient biofuel.
Keywords: Functional nanomaterials, nanocatalysts, biodiesel production, transesterification catalysts, esterification catalysts, magnetic nanomaterials, mesoporous catalyst