Cu (II) Complex of 1- Naphthaldehyde Semicarbazone: Synthesis, Characterization, Thermal Analysis and Antibacterial Activity

Main Article Content

Dipta Sarker
Md. Faruk Hossen
Md. Kudrat-E-Zahan
Md. Masuqul Haque
Rausan Zamir
Md. Ali Asraf

Abstract

The ligand, L is the Schiff base formed by condensation of 1- naphthaldehyde with semicarbazide and its Cu(II) complex have been synthesized and characterized by elemental and thermogravimetric analysis and molar conductivity, magnetic and spectroscopic measurements. Elemental analysis of the chelate suggests the stoichiometry is 1:1 (metal-ligand). Infrared spectra of the complex agree with the coordination to the central metal atom through the nitrogen of the azomethine (-HC=N-) group and the carbonyl oxygen atom. Magnetic susceptibility data suggest a tetrahedral geometry for the complex. ESI-MS data also supports the proposed structure of the synthesized compounds. The ligand and its copper complex have been screened for their antibacterial activity against Enterobacter aerogenes and Bacillus cereus. The metal complex were shown to possess more antibacterial activity than the uncomplexed ligand.

Keywords:
Semicarbazone, complexation, thermogravimetric analysis, antibacterial activity

Article Details

How to Cite
Sarker, D., Hossen, M. F., Kudrat-E-Zahan, M., Haque, M. M., Zamir, R., & Asraf, M. A. (2020). Cu (II) Complex of 1- Naphthaldehyde Semicarbazone: Synthesis, Characterization, Thermal Analysis and Antibacterial Activity. Asian Journal of Advanced Research and Reports, 10(1), 1-9. https://doi.org/10.9734/ajarr/2020/v10i130231
Section
Original Research Article

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